| 1 | » Sébastien Buemi (CH)
» Brendon Hartley (NZ)
» Ryo Hirakawa (J) | Toyota GR010 HYBRID | Toyota Gazoo Racing | 27 | 1:31,795 | | 182,480 |
| 2 | » Alessandro Pier Guidi (I)
» James Calado (GB)
» Antonio Giovinazzi (I) | Ferrari 499P | Ferrari AF Corse | 28 | 1:31,984 | 0:00,189 | 182,105 |
| 3 | » Kamui Kobayashi (J)
» José Maria López (RA)
» Mike Conway (GB) | Toyota GR010 HYBRID | Toyota Gazoo Racing | 27 | 1:32,073 | 0:00,278 | 181,929 |
| 4 | » Loic Duval (F)
» Nico Müller (CH)
» Gustavo Menezes (USA) | Peugeot 9X8 | Peugeot TotalEnergies | 30 | 1:32,738 | 0:00,943 | 180,624 |
| 5 | » Earl Bamber (NZ)
» Richard Westbrook (GB)
» Alex Lynn (GB) | Cadillac V-Series.R | Cadillac Racing | 27 | 1:32,818 | 0:01,023 | 180,469 |
| 6 | » Jacques Villeneuve (CDN)
» Esteban Guerrieri (RA)
» Tom Dillmann (F) | Vanwall Vandervell 680 | Floyd Vanwall Racing Team | 25 | 1:32,922 | 0:01,127 | 180,267 |
| 7 | » Miguel Molina (E)
» Antonio Fuoco (I)
» Nicklas Nielsen (DK) | Ferrari 499P | Ferrari AF Corse | 29 | 1:32,980 | 0:01,185 | 180,154 |
| 8 | » André Lotterer (D)
» Laurens Vanthoor (B)
» Kévin Estre (F) | Porsche 963 | Porsche Penske Motorsport | 29 | 1:33,222 | 0:01,427 | 179,687 |
| 9 | » Frédéric Makowiecki (F)
» Dane Cameron (USA)
» Michael Christensen (DK) | Porsche 963 | Porsche Penske Motorsport | 28 | 1:33,467 | 0:01,672 | 179,216 |
| 10 | » Paul di Resta (GB)
» Jean-Éric Vergne (F)
» Mikkel Jensen (DK) | Peugeot 9X8 | Peugeot TotalEnergies | 26 | 1:33,709 | 0:01,914 | 178,753 |
| 11 | » Ryan Briscoe (AUS)
» Romain Dumas (F)
» Olivier Pla (F) | Glickenhaus 007 LMH | Glickenhaus Racing | 27 | 1:33,900 | 0:02,105 | 178,389 |
| 12 | » Ryan Cullen (IRL)
» Gabriel Aubry (F)
» Matthias Kaiser (FL) | ORECA 07 | Vector Sport | 28 | 1:34,265 | 0:02,470 | 177,699 |
| 13 | » Robert Kubica (PL)
» Louis Delétraz (CH)
» Rui Andrade (P) | ORECA 07 | Team WRT | 22 | 1:34,267 | 0:02,472 | 177,695 |
| 14 | » Robin Frijns (NL)
» Sean Gelael (RI)
» Ferdinand Habsburg (A) | ORECA 07 | Team WRT | 25 | 1:34,497 | 0:02,702 | 177,262 |
| 15 | » António Félix da Costa (P)
» Yifei Ye (RC)
» David Beckmann (D) | ORECA 07 | Hertz Team JOTA | 23 | 1:34,509 | 0:02,714 | 177,240 |
| 16 | » Benjamin Hanley (GB)
» Philip Hanson (GB)
» Freddie Lubin (GB) | ORECA 07 | United Autosports | 27 | 1:34,535 | 0:02,740 | 177,191 |
| 17 | » Mirko Bortolotti (I)
» Daniil Kvyat (RUS)
» Doriane Pin (F) | ORECA 07 | Prema Racing | 28 | 1:34,538 | 0:02,743 | 177,185 |
| 18 | » Oliver Jarvis (GB)
» Giedo van der Garde (NL)
» Josh Pierson (USA) | ORECA 07 | United Autosports | 22 | 1:34,640 | 0:02,845 | 176,994 |
| 19 | » Bent Viscaal (NL)
» Filip-Ioan Ugran (RO)
» Juan Manuel Correa (USA) | ORECA 07 | Prema Racing | 27 | 1:34,671 | 0:02,876 | 176,936 |
| 20 | » Memo Rojas (MEX)
» André Negrão (BR)
» Olli Caldwell (GB) | ORECA 07 | Alpine Elf Endurance Team | 15 | 1:35,308 | 0:03,513 | 175,754 |
| 21 | » Julien Canal (F)
» Matthieu Vaxivière (F)
» Charles Milesi (F) | ORECA 07 | Alpine Elf Endurance Team | 23 | 1:35,445 | 0:03,650 | 175,502 |
| 22 | » David Heinemeier Hansson (DK)
» Pietro Fittipaldi (BR)
» Oliver Rasmussen (DK) | ORECA 07 | JOTA | 24 | 1:35,449 | 0:03,654 | 175,494 |
| 23 | » Albert Costa (E)
» Jakub Smiechowski (PL)
» Fabio Scherer (CH) | ORECA 07 | Inter Europol Competition | 26 | 1:35,874 | 0:04,079 | 174,716 |
| 24 | » Davide Rigon (I)
» Francesco Castellacci (I)
» Thomas Flohr (CH) | Ferrari 488 GTE Evo | AF Corse | 26 | 1:40,426 | 0:08,631 | 166,797 |
| 25 | » Luis Pérez-Companc (RA)
» Alessio Rovera (I)
» Lilou Wadoux (F) | Ferrari 488 GTE Evo | Richard Mille AF Corse | 26 | 1:40,790 | 0:08,995 | 166,195 |
| 26 | » Rahel Frey (CH)
» Michelle Gatting (DK)
» Sarah Bovy (B) | Porsche 911 RSR-19 | Iron Dames | 25 | 1:40,899 | 0:09,104 | 166,015 |
| 27 | » Matteo Cressoni (I)
» Alessio Picariello (B)
» Claudio Schiavoni (I) | Porsche 911 RSR-19 | Iron Lynx | 25 | 1:40,936 | 0:09,141 | 165,954 |
| 28 | » Daniel Serra (BR)
» Takeshi Kimura (J)
» Scott Huffaker (USA) | Ferrari 488 GTE Evo | Kessel Racing | 25 | 1:40,948 | 0:09,153 | 165,934 |
| 29 | » Mike Wainwright (GB)
» Ben Barker (GB)
» Riccardo Pera (I) | Porsche 911 RSR-19 | GR Racing | 25 | 1:41,094 | 0:09,299 | 165,695 |
| 30 | » Harry Tincknell (GB)
» Zacharie Robichon (CDN)
» Ryan Hardwick (USA) | Porsche 911 RSR-19 | Proton Competition | 22 | 1:41,107 | 0:09,312 | 165,673 |
| 31 | » Ahmad Al Harthy (OM)
» Charlie Eastwood (GB)
» Michael Dinan (USA) | Aston Martin Vantage AMR | ORT by TF | 27 | 1:41,449 | 0:09,654 | 165,115 |
| 32 | » Miguel Ramos (P)
» Matteo Cairoli (I)
» Guilherme Oliveira (P) | Porsche 911 RSR-19 | Project 1 - AO | 23 | 1:41,502 | 0:09,707 | 165,029 |
| 33 | » Diego Alessi (I)
» Simon Mann (USA)
» Ulysse De Pauw (B) | Ferrari 488 GTE Evo | AF Corse | 26 | 1:41,711 | 0:09,916 | 164,690 |
| 34 | » Nicky Catsburg (NL)
» Ben Keating (USA)
» Nicolas Varrone (RA) | Chevrolet Corvette C8.R | Corvette Racing | 26 | 1:41,751 | 0:09,956 | 164,625 |
| 35 | » Tomonobu Fujii (J)
» Satoshi Hoshino (J)
» Casper Stevenson (GB) | Aston Martin Vantage AMR | D'Station Racing | 23 | 1:41,752 | 0:09,957 | 164,623 |
| 36 | » Nicki Thiim (DK)
» Paul Dalla Lana (CDN)
» Axcil Jefferies (ZW) | Aston Martin Vantage AMR | Northwest AMR | 26 | 1:41,789 | 0:09,994 | 164,563 |
| 37 | » Christian Ried (D)
» Julien Andlauer (F)
» Mikkel Overgaard Pedersen (DK) | Porsche 911 RSR-19 | Dempsey-Proton Racing | 25 | 1:41,791 | 0:09,996 | 164,560 |
