| 1 | » Paul di Resta (GB)
» Jean-Éric Vergne (F)
» Mikkel Jensen (DK) | Peugeot 9X8 | Peugeot TotalEnergies | 39 | 1:49,613 | | 177,745 |
| 2 | » Sébastien Buemi (CH)
» Brendon Hartley (NZ)
» Ryo Hirakawa (J) | Toyota GR010 HYBRID | Toyota Gazoo Racing | 44 | 1:49,658 | 0:00,045 | 177,672 |
| 3 | » Nicolas Lapierre (F)
» André Negrão (BR)
» Matthieu Vaxivière (F) | Alpine A480 | Alpine Elf Endurance Team | 37 | 1:49,690 | 0:00,077 | 177,620 |
| 4 | » Kamui Kobayashi (J)
» José Maria López (RA)
» Mike Conway (GB) | Toyota GR010 HYBRID | Toyota Gazoo Racing | 43 | 1:49,773 | 0:00,160 | 177,486 |
| 5 | » François Perrodo (F)
» Nicklas Nielsen (DK)
» Alessio Rovera (I) | ORECA 07 | AF Corse | 9 | 1:51,787 | 0:02,174 | 174,288 |
| 6 | » Filipe Albuquerque (P)
» Philip Hanson (GB)
» Will Owen (USA) | ORECA 07 | United Autosports USA | 37 | 1:51,993 | 0:02,380 | 173,968 |
| 7 | » René Rast (D)
» Robin Frijns (NL)
» Sean Gelael (RI) | ORECA 07 | WRT | 39 | 1:52,107 | 0:02,494 | 173,791 |
| 8 | » Loic Duval (F)
» Nico Müller (CH)
» Gustavo Menezes (USA) | Peugeot 9X8 | Peugeot TotalEnergies | 41 | 1:52,147 | 0:02,534 | 173,729 |
| 9 | » Oliver Jarvis (GB)
» Alex Lynn (GB)
» Josh Pierson (USA) | ORECA 07 | United Autosports USA | 37 | 1:52,159 | 0:02,546 | 173,710 |
| 10 | » Esteban Gutiérrez (MEX)
» Alex Brundle (GB)
» Jakub Smiechowski (PL) | ORECA 07 | Inter Europol Competition | 38 | 1:52,279 | 0:02,666 | 173,524 |
| 11 | » Edward Jones (GB)
» Jonathan Aberdein (ZA)
» Oliver Rasmussen (DK) | ORECA 07 | JOTA | 36 | 1:52,379 | 0:02,766 | 173,370 |
| 12 | » Paul-Loup Chatin (F)
» Charles Milesi (F)
» Lilou Wadoux (F) | ORECA 07 | Richard Mille Racing Team | 37 | 1:52,435 | 0:02,822 | 173,284 |
| 13 | » Robert Kubica (PL)
» Louis Delétraz (CH)
» Lorenzo Colombo (I) | ORECA 07 | Prema ORLEN Team | 39 | 1:52,760 | 0:03,147 | 172,784 |
| 14 | » Norman Nato (F)
» Ferdinand Habsburg (A)
» Rui Andrade (P) | ORECA 07 | Realteam by WRT | 37 | 1:52,796 | 0:03,183 | 172,729 |
| 15 | » Rene Binder (A)
» James Allen (AUS)
» Steven Thomas (USA) | ORECA 07 | Algarve Pro Racing | 41 | 1:52,881 | 0:03,268 | 172,599 |
| 16 | » António Félix da Costa (P)
» Will Stevens (GB)
» Roberto Gonzalez (MEX) | ORECA 07 | JOTA | 39 | 1:53,178 | 0:03,565 | 172,146 |
| 17 | » Sébastien Bourdais (F)
» Renger van der Zande (NL)
» Ryan Cullen (IRL) | ORECA 07 | Vector Sport | 37 | 1:53,379 | 0:03,766 | 171,841 |
| 18 | » Miroslav Konopka (SK)
» Mathias Beche (CH)
» Richard Bradley (GB) | ORECA 07 | ARC Bratislava | 40 | 1:53,626 | 0:04,013 | 171,467 |
| 19 | » Matthieu Lahaye (F)
» Jean-Baptiste Lahaye (F)
» François Heriau (F) | ORECA 07 | Ultimate | 36 | 1:55,056 | 0:05,443 | 169,336 |
| 20 | » Michael Christensen (DK)
» Kévin Estre (F) | Porsche 911 RSR-19 | Porsche GT Team | 36 | 1:57,192 | 0:07,579 | 166,250 |
| 21 | » Alessandro Pier Guidi (I)
» James Calado (GB) | Ferrari 488 GTE Evo | AF Corse | 38 | 1:57,995 | 0:08,382 | 165,118 |
| 22 | » Miguel Molina (E)
» Antonio Fuoco (I) | Ferrari 488 GTE Evo | AF Corse | 41 | 1:58,391 | 0:08,778 | 164,566 |
| 23 | » Richard Lietz (A)
» Gianmaria Bruni (I) | Porsche 911 RSR-19 | Porsche GT Team | 41 | 1:58,514 | 0:08,901 | 164,395 |
| 24 | » Tommy Milner (USA)
» Nick Tandy (GB) | Chevrolet Corvette C8.R | Corvette Racing | 38 | 1:58,826 | 0:09,213 | 163,964 |
| 25 | » Nicolas Leutwiler (CH)
» Matteo Cairoli (I)
» Mikkel Overgaard Pedersen (DK) | Porsche 911 RSR-19 | Team Project 1 | 38 | 1:59,717 | 0:10,104 | 162,743 |
| 26 | » Christian Ried (D)
» Harry Tincknell (GB)
» Seb Priaulx (GB) | Porsche 911 RSR-19 | Dempsey-Proton Racing | 31 | 1:59,859 | 0:10,246 | 162,550 |
| 27 | » Jan Heylen (B)
» Fred Poordad (USA)
» Patrick Lindsey (USA) | Porsche 911 RSR-19 | Dempsey-Proton Racing | 40 | 2:00,019 | 0:10,406 | 162,334 |
| 28 | » Francesco Castellacci (I)
» Nick Cassidy (NZ)
» Thomas Flohr (CH) | Ferrari 488 GTE Evo | AF Corse | 39 | 2:00,224 | 0:10,611 | 162,057 |
| 29 | » Toni Vilander (FIN)
» Christoph Ulrich (CH)
» Simon Mann (USA) | Ferrari 488 GTE Evo | AF Corse | 40 | 2:00,764 | 0:11,151 | 161,332 |
| 30 | » Giancarlo Fisichella (I)
» Matteo Cressoni (I)
» Claudio Schiavoni (I) | Ferrari 488 GTE Evo | Iron Lynx | 37 | 2:00,792 | 0:11,179 | 161,295 |
| 31 | » Nicki Thiim (DK)
» Paul Dalla Lana (CDN)
» David Pittard (GB) | Aston Martin Vantage AMR | Northwest AMR | 36 | 2:01,073 | 0:11,460 | 160,921 |
| 32 | » Marco Sørensen (DK)
» Ben Keating (USA)
» Henrique Chaves Jr. (P) | Aston Martin Vantage AMR | TF Sport | 37 | 2:01,074 | 0:11,461 | 160,919 |
| 33 | » Mike Wainwright (GB)
» Ben Barker (GB)
» Riccardo Pera (I) | Porsche 911 RSR-19 | GR Racing | 34 | 2:01,216 | 0:11,603 | 160,731 |
| 34 | » Gunnar Jeannette (USA)
» Ben Barnicoat (GB)
» PJ Hyett (USA) | Porsche 911 RSR-19 | Team Project 1 | 38 | 2:01,217 | 0:11,604 | 160,729 |
| 35 | » Tomonobu Fujii (J)
» Satoshi Hoshino (J)
» Charlie Fagg (GB) | Aston Martin Vantage AMR | D'Station Racing | 36 | 2:01,535 | 0:11,922 | 160,309 |
| 36 | » Pierre Ragues (F)
» Gabriel Aubry (F)
» Franck Dezoteux (F) | Ferrari 488 GTE Evo | Spirit of Race | 7 | 2:01,609 | 0:11,996 | 160,211 |
| 37 | » Rahel Frey (CH)
» Michelle Gatting (DK)
» Sarah Bovy (B) | Ferrari 488 GTE Evo | Iron Dames | 40 | 2:01,707 | 0:12,094 | 160,082 |
